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MCQs 1:

Which form(s) can carboxylic acid take?





Topic: Types of Carboxylic Acids

Correct Answer: C) Both A and B

Detailed Hint:
  • Carboxylic acids can occur in various forms, and both aliphatic and aromatic structures are possible.
  • In an aliphatic carboxylic acid, the functional group COOH is attached to a straight or branched chain of carbon atoms (R-COOH).
  • In the case of aromatic carboxylic acids, the COOH is attached to an aromatic (Ar) group, typically a phenyl group (Ar-COOH).

MCQs 2:

What can carboxylic acids be reduced to when reacted with LiAlH4?





Topic: Reactions of Carboxylic Acids

Correct Answer: B) Alcohols

Detailed Hint:
  • The reduction reaction of carboxylic acids is not as straightforward as with aldehydes, ketones, or esters.
  • Carboxylic acids can be reduced to primary alcohols specifically when using Lithium aluminium hydride (LiAlH4), a strong reducing agent.

MCQs 3:

What is the product formed when acetic acid reacts with PCl5?





Topic: Reactions of Acetic Acid

Correct Answer: B) CH3COCl

Detailed Hint:
  • The reaction of acetic acid with phosphorus pentachloride (PCl5) results in the formation of acetyl chloride (CH3COCl).
  • Side products of this reaction include phosphorus oxychloride (POCl3) and hydrochloric acid (HCl).

MCQs 4:

Which of the following substances will yield acetic acid upon oxidation?





Topic: Oxidation Reactions to form Acetic Acid

Correct Answer: A) Ethanol

Detailed Hint:
  • The oxidation of alcohols can produce a variety of products.
  • In the case of ethanol, its oxidation leads to the formation of acetic acid.

MCQs 5:

Which of the following organic acids lacks a carboxyl group?





Topic: Organic Acid Structures

Correct Answer: B) Picric acid

Detailed Hint:
  • Organic acids typically contain a carboxyl group as a fundamental feature of their structure.
  • Picric acid, also known as Trinitrophenol, is an exception to this rule as it does not contain a carboxyl group.

MCQs 6:

What class of compounds is produced when carboxylic acids react with alcohols?





Topic: Reactions of Carboxylic Acids

Correct Answer: B) Esters

Detailed Hint:
  • Carboxylic acids react with alcohols in a process known as esterification.
  • The outcome of this reaction is the formation of esters.

MCQs 7:

What is the IUPAC name for caproic acid?





Topic: Nomenclature of Carboxylic Acids

Correct Answer: B) Hexanoic acid

Detailed Hint:
  • IUPAC nomenclature is a systematic method of naming chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC).
  • Caproic acid, derived from hexane, is officially named Hexanoic acid with the chemical formula CH3​(CH2​)4​COOH.

Question 8:

What is the name of the reaction that occurs when alcohol reacts with acetic acid?





Topic: Esterification

Correct Answer: B) Esterification

Detailed Hint:
  • The combination of an alcohol and acetic acid results in a particular type of chemical reaction.
  • This reaction results in the formation of an ester and is therefore termed as esterification.

Question 9:

What physical state are the first three aliphatic acids typically in?





Topic: Properties of Aliphatic Acids

Correct Answer: A) Liquids

Detailed Hint:
  • Aliphatic acids, such as formic acid, acetic acid, and propionic acid, have unique physical properties.
  • Notably, these first three aliphatic acids are colorless and exist in a liquid state.

Question 10:

Which of the following is identified as a strong reducing agent?





Topic: Reducing Agents

Correct Answer: D) Chloroacetic acid

Detailed Hint:
  • Reducing agents are substances that lose or "donate" electrons in a chemical reaction.
  • Chloroacetic acid is recognized as a strong reducing agent owing to its high acidic strength.

Question 11:

What substance is found in the stings of bees and wasps?





Topic: Composition of Animal Stings

Correct Answer: B) Formic acid

Detailed Hint:
  • Animal stings, particularly those of bees and wasps, contain specific substances that cause irritation.
  • Formic acid, represented by the chemical formula HCOOH, is the primary substance present in these stings. The discomfort caused by stings is largely due to this acid.

Question 12:

What is used as a coagulant for latex in the rubber industry?





Topic: Industrial Use of Acids

Correct Answer: A) Acetic acid

Detailed Hint:
  • Certain acids are used in industry for specific purposes.
  • In the rubber industry, acetic acid, CH₃COOH, is commonly employed as a coagulant for latex.

Question 13:

What is the correct order of ease of esterification of the following acids with CH3OH?

I. HCOOH

II. CH3COOH

III. CH3CH2COOH





Topic: Esterification of Acids

Correct Answer: D) III < II < I

Detailed Hint:
  • The process of esterification varies depending on the size and structure of the alkyl group in the carboxylic acid (R–COOH).
  • The ease of esterification tends to be greater with smaller alkyl groups.

Question 14:

What is the characteristic that gives the name 'glacial' to pure acetic acid?





Topic: Physical Properties of Acetic Acid

Correct Answer: B) It forms an ice-like solid below 17˚C

Detailed Hint:
  • The term 'glacial' is used to describe certain physical properties of acetic acid.
  • Notably, pure acetic acid takes on an ice-like solid form when cooled below 17˚C, hence the name 'glacial acetic acid'.

Question 15:

Which of the following agents can directly reduce carboxylic acid to primary alcohols?





Topic: Reduction of Carboxylic Acid

Correct Answer: A) LiAlH4

Detailed Hint:
  • Carboxylic acids can be reduced to primary alcohols using certain agents.
  • Among the options listed, LiAlH4 (lithium aluminium hydride) is recognized as a strong reducing agent capable of directly converting carboxylic acids into primary alcohols.

Question 17:

Which substance among the following has both hydroxyl and carboxylic acid groups?





Topic: Identification of Functional Groups

Correct Answer: D) Salicylic acid

Detailed Hint:
  • Functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules.
  • Among the given options, salicylic acid is unique because it contains both a hydroxyl group (-OH) and a carboxylic acid group (-COOH).

Question 18:

What is the general formula for aliphatic carboxylic acid?





Topic: Formulas of Organic Compounds

Correct Answer: C) CnH2nO2

Detailed Hint:
  • Organic compounds are a broad class of substances characterized by carbon-based molecules. They have specific general formulas that provide a simplified representation of their chemical structure.
  • The general formula for aliphatic carboxylic acids is CnH2nO2, which indicates the presence of a carboxyl functional group (-COOH) in these compounds.

Question 19:

Which among the following substances is associated with an orange flavor?





Topic: Flavor Profiles of Chemical Compounds

Correct Answer: B) Octyl Acetate

Detailed Hint:
  • Certain chemicals are known to contribute specific flavors or aromas to foods and other substances.
  • Octyl acetate, for instance, is associated with an orange flavor. This ester is often used in the production of artificial flavors due to its distinctive citrus aroma.

Question 20:

What is the boiling point of formic acid?





Topic: Physical Properties of Acids

Correct Answer: A) 100°C

Detailed Hint:
  • The boiling point of an acid is the temperature at which it transitions from a liquid to a gas.
  • Formic acid, also known as methanoic acid, has a boiling point of 100°C, which is a fundamental aspect of its physical properties.

Question 21:

What is the IUPAC name for a carboxylic acid that contains three carbon atoms?





Topic: Nomenclature of Organic Compounds

Correct Answer: C) Propanoic acid

Detailed Hint:
  • The International Union of Pure and Applied Chemistry (IUPAC) provides the universally accepted naming system for organic compounds.
  • In this system, a carboxylic acid with three carbon atoms is named propanoic acid, following the rule that the prefix 'prop-' indicates the presence of three carbon atoms.

Question 22:

Which test is commonly used for the identification of amino acids?





Topic: Biochemical Test for Amino Acids

Correct Answer: A) Ninhydrin test

Detailed Hints:
  • Different tests are used in biochemistry to detect and identify amino acids.
  • The Ninhydrin test is particularly recognized for its effectiveness in identifying amino acids, as it reacts with these molecules to form a characteristic bluish-violet product, making it an essential tool in biochemical analysis.

Question 23:

What is another name for 2-Hydroxy propionic acid?





Topic: Nomenclature of Organic Acids

Correct Answer: B) Lactic acid

Detailed Hints:
  • Organic acids can have both a scientific name and a common name, which are often used interchangeably.
  • 2-Hydroxy propionic acid is commonly known as lactic acid.

Question 24:

What is the description of Glacial acetic acid?





Topic: Characteristics of Organic Acids

Correct Answer: D) Pure acetic acid at 17°C

Detailed Hints:
  • The term "glacial" is used to describe the physical state of acetic acid when it freezes, which occurs at 17°C.
  • Therefore, glacial acetic acid refers to the pure, undiluted substance at 17°C.

Question 25:

In what kind of solution does carboxylic acid exist as a cyclic dimer?





Topic: Physical Behavior of Carboxylic Acids

Correct Answer: C) Benzene

Detailed Hints:
  • Carboxylic acids can form a cyclic dimer structure due to hydrogen bonding when in a specific type of solution.
  • In the case of benzene, which is non-polar, carboxylic acid will exist as a cyclic dimer.

Question 26:

How many essential amino acids are there?





Topic: Classification of Amino Acids

Correct Answer: B) 10

Detailed Hints:
  • Amino acids are categorized into two groups: essential and non-essential.
  • Essential amino acids are those that the human body cannot produce on its own and must obtain through diet. There are 10 such essential amino acids.

Question 27:

What is the term for the reaction between a fat and caustic soda?





Topic: Chemical Reactions of Fats

Correct Answer: D) Saponification

Detailed Hints:
  • Different reactions can occur between fats and other substances.
  • The reaction between a fat and caustic soda specifically results in the production of soap and is known as saponification.

Question 28:

Which acid's solution is typically used for seasoning food?





Topic: Usage of Acids in Culinary

Correct Answer: B) Acetic acid

Detailed Hints:
  • Acids have various uses, including in the culinary world.
  • Acetic acid, in particular, is used as a souring agent in foods like vinegar and pickled vegetables, contributing to their unique flavors.

Question 29:

Why does acetic acid exhibit a molecular mass of 120 when dissolved in benzene?





Topic: Behavior of Acetic Acid in Different Solvents

Correct Answer: D) As a result of dimerization

Detailed Hint:
  • The observed molecular mass of a substance can be influenced by its behavior in different solvents.
  • When acetic acid is dissolved in benzene, it forms a dimer structure, which effectively doubles its molecular mass. Hence, the observed molecular mass is 120.

Question 30:

Which acid is used in the production of synthetic rubber?





Topic: Industrial Applications of Acids

Correct Answer: A) Acetic acid

Detailed Hint:
  • Various acids have diverse applications in the industrial sector.
  • Acetic acid is specifically used as a coagulant in the rubber industry during the manufacture of synthetic rubber.

Question 31:

What is the role of acetic acid in the laboratory?





Topic: Laboratory Applications of Acids

Correct Answer: D) As a solvent for carrying out reactions

Detailed Hint:
  • Acids are not only used in industries but also have significant roles in scientific laboratories.
  • Particularly, acetic acid is used as a solvent in laboratories for carrying out various reactions.